The Organic Chemistry of Enzyme-Catalyzed Reactions Chapter 8 Decarboxylation

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Plan 8.1. Decarboxylation Reactions Driving power for decarboxylation. Plan 8.2. Decarboxylation is quickened in corrosive. Decarboxylation of ?- Keto Acids. Plan 8.3. Solid acids are expected to protonate carbonyls (pKa - 7). Cyclic Transition State for Decarboxylation of ?- Keto Acids. Plan 8.4. Protonation of Imines (pKa around 7) is Easy.

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